Interfacial motion arises in two different ways: 1) as the motion of two-dimensional level sets during gradient flow of an integral over volume; 2) as a velocity normal to a surface, where the velocity is gradient flow of a surface integral. The first method is discussed in Section 3.2.1.
The second approach has been discussed above and appears in tables I and in table II in small slope approximation and as the graph of a function z(x,y), respectively, for isotropic surfaces. For anisotropic surfaces, the energy functional is a surface integral: . The interfacial surface energy density, , does not necessarily have continuous derivatives of the surface orientation ; in fact, need not be continuous. Furthermore, the surface S can have edges and corners where its derivatives are discontinuous; furthermore it can have flat facets. In this case, the variational derivative is the instantaneous increase in interfacial area due to a normal velocity v, weighted by the surface energy density, and is called the `weighted mean curvature' [6]. When is isotropic, is equal to , where is the geometric mean curvature. In two dimensions, , when is twice differentiable with respect to the polar angle , which is the the Herring formulation[7]. Generally, , where is the Cahn-Hoffman capillarity vector[6, 8, 9, 4].
The anisotropic version of gradient flow for the surface integrals is summarized
in the following table: